The Age of the Earth

4.6 billion years (4,600,000,000 years)

What We Know, How We Know and How We Got There

Early Ideas of the Age of the Earth

1654 

Archbishop Usher (Ireland), used genealogy in the Bible to calculate that
 the Earth was created October 26, 4004 BC, 9:00 am
Earth was thus 6000 years old.

Led to the Doctrine of Catastrophism:
Earth was shaped by series of giant disasters.
Had to fit many processes into a short time scale.

1770's, 1780's

 "Revolution"
James Hutton, Father of Geology (Scotland) 1726-1797.
Published Theory of the Earth in 1785.

Hadrian's Wall built by Romans, after 1500 years no change. Suspected that Earth was then much older.

1897 

Quantitative Scientific Methods

Lord Kelvin assumed that the Earth was originally molten and calculated a date based on cooling through conduction and radiation.
Age of Earth was calculated to be about 24-40 million years.

1899 - 1901

John Joly calculated the rate of delivery of salt to the ocean. River water has only a small concentration of salts. Rivers flow to the sea. Evaporative concentration of salts.

Age of Ocean = Total salt in oceans (in grams) divided by rate of salt added (grams per year)

Age of Earth was calculated to be 90-100 million years.

Radiometric Dating
or,
How do we determine the age of a rock?

Principles of Radiometric Dating

Naturally-occurring radioactive materials break down into other materials at known rates. This is known as radioactive decay.

Radioactive parent elements decay to stable daughter elements.

Radioactivity was discovered in 1896 by Henri Becquerel. In 1905, Rutherford and Boltwood used the principle of radioactive decay to measure the age of rocks and minerals (using Uranium decaying to produce Helium. Uranium decay produces He, leading to a date of 500 million years.  Boltwood suspected that lead was the stable end product of the decay of uranium.   In 1907, Boltwood dated a sample of urnanite based on uranium/lead ratios.  Published the age of a sample of urananite based on Uranium-Lead dating. Date was 1.64 billion years.  Amazingly, this was all done before isotopes were known, and before the decay rates were known accurately.

The invention of the MASS SPECTROMETER after World War I (post-1918) led to the discovery of more than 200 isotopes.

Many radioactive elements can be used as geologic clocks. Each radioactive element decays at its own nearly constant rate. Once this rate is known, geologists can estimate the length of time over which decay has been occurring by measuring the amount of radioactive parent element and the amount of stable daughter elements.

Radioactive parent isotopes and their stable daughter products

Radioactive Parent

Stable Daughter

Potassium 40

Argon 40

Rubidium 87

Strontium 87

Thorium 232

Lead 208

Uranium 235

Lead 207

Uranium 238

Lead 206

Carbon 14

Nitrogen 14

In the above table, note that the number is the mass number (the total number of protons plus neutrons).
Note that the mass number may vary for an element, because of a differing number of neutrons.
Elements with various numbers of neutrons are called isotopes of that element.

Each radioactive isotope has its own unique half-life.
A half-life is the time it takes for half of the parent radioactive element to decay to a daughter product.

Half Lives for Radioactive Elements

Radioactive Parent

Stable Daughter

Half life

Potassium 40

Argon 40

1.25 billion yrs

 

Rubidium 87

Strontium 87

48.8 billion yrs

Thorium 232

Lead 208

14 billion years

Uranium 235

Lead 207

704 million years

Uranium 238

Lead 206

4.47 billion years

Carbon 14

Nitrogen 14

5730 years

Radioactive decay occurrs at a constant exponential or geometric rate.
The rate of decay is proportional to the number of parent atoms present.

The proportion of parent to daughter atoms tells us the number of half-lives, which we can use to find the age in years.
For example, if there are equal amounts of parent and daughter, then one half-life has passed.
If there is three times as much daughter as parent, then two half-lives have passed. (see graph, above)

Radioactive decay occurs by releasing particles and energy.

Uranium decays producing subatomic particles, energy, and lead.

As uranium-238 decays to lead, there are 13 intermediate radioactive daughter products formed (including radon, polonium, and other isotopes of uranium), and 8 alpha particles and 6 beta particles released. There are three types of subatomic particles involved:

  1. Alpha particles
    large, easily stopped by paper
    charge = +2
    mass = 4
  2. Beta particles
    penetrate hundreds of times farther than alpha particles, but easily stopped compared with neutrons and gamma rays.
    charge = -1
    mass = negligible
  3. neutrons
    highly penetrating
    no charge
    mass = 1
Gamma rays (high energy X-rays) are also produced.
    Highly penetrating electromagnetic radiation. Photons (light).
    No charge or mass.
    Can penetrate concrete. Lead shield can be used.

So how does Carbon-14 dating work?

  1. Cosmic rays from the sun strike Nitrogen 14 atoms in the atmosphere and cause them to turn into radioactive Carbon 14, which combines with oxygen to form radioactive carbon dioxide.
  2. Living things are in equilibrium with the atmosphere, and the radioactive carbon dioxide is absorbed and used by plants. The radioactive carbon dioxide gets into the food chain and the carbon cycle.
  3. All living things contain a constant ratio of Carbon 14 to Carbon 12. (1 in a trillion).
  4. At death, Carbon 14 exchange ceases and any Carbon 14 in the tissues of the organism begins to decay to Nitrogen 14, and is not replenished by new C-14.
  5. The change in the Carbon 14 to Carbon 12 ratio is the basis for dating.
  6. The half-life is so short (5730 years) that this method can only be used on materials less than 70,000 years old. Archaeological dating uses this method.) Also useful for dating the Pleistocene Epoch (Ice Ages).
  7. Assumes that the rate of Carbon 14 production (and hence the amount of cosmic rays striking the Earth) has been constant (through the past 70,000 years).

So far, oldest dated Earth rocks are 3.96 billion years.


Older rocks include meteorites and moon rocks with dates on the order of 4.6 billion years.
Moon rocks, highland ~ 4.5 by, mare basalt ~ 3.2 - 3.8 by
Meteorites - older than 4.5 by

Mass spectrograph was used after WWI (1918). Led to the discovery of over 200 isotopes.

Many radioactive elements can be used as geologic clocks. Each element decays at its own nearly constant rate. Once this decay rate is known, geologists can estimate the length of time over which decay has been occurring by measuring the amount of radioactive parent and the amount of stable daughter elements.

 

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